3082-64-2, Name is (R)-1-Phenylpropan-1-amine, molecular formula is C9H13N, Product Details of 3082-64-2, belongs to chiral-catalyst compound, is a common compound. In a patnet, author is Zhao, Xiao-Jing, once mentioned the new application about 3082-64-2.
A challenging direct asymmetric catalytic aerobic oxidative cross-coupling of 2-naphthylamine and 2-naphthol, using a novel Cu-I/SPDO system, has been successfully developed for the first time. Enantioenriched 3,3 ‘-disubstituted NOBINs were achieved and could be readily derived to divergent chiral ligands and catalysts. This reaction features high enantioselectivities (up to 96 % ee) and good yields (up to 80 %). The DFT calculations suggest that the F-H interactions between CF3 of L17 and H-1,8 of 2-naphthol, and the pi-pi stacking between the two coupling partners could play vital roles in the enantiocontrol of this cross-coupling reaction.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 3082-64-2 help many people in the next few years. Product Details of 3082-64-2.
Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare