Electric Literature of 1436-59-5, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 1436-59-5, C6H14N2. A document type is Article, introducing its new discovery.
The first metal phosphate containing a chiral amine, [(1R,2R)-C6H10(NH3) 2][Ga(OH)(HPO4)2]·H2O, has been synthesized hydrothermally and characterized by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21 with a = 8.7202(2) A, b = 7.1276(2) A, c = 11.1411(4) A, beta= 96.129(1), and Z = 2. The structure consists of infinite chains of trans-corner-sharing GaO5(OH) octahedra with the adjacent octahedra being bridged by HPO4 groups, which are H-bonded with amine groups of the organic cations and the lattice water. The Ga-O bond lengths along the backbone of the chain are alternately short and long. For comparison, the . gallophosphate-containing racemic mix is also synthesized. [trans-1,2-C6H10(NH3) 2][Ga(OH)(HPO4)2]·H2O crystallizes in the centrosymmetric, orthorhombic space group Pbcm with a = 8.6993(2) A, b = 21.8612(1) A, c = 7.1557(2) A, V = 1360.85(5) A3, and Z = 4.
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