Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Park, Dongseong, once mentioned the application of 144163-85-9, Name is tert-Butyl ((2S,4S,5S)-5-amino-4-hydroxy-1,6-diphenylhexan-2-yl)carbamate, molecular formula is C23H32N2O3, molecular weight is 384.5118, MDL number is MFCD09833420, category is chiral-catalyst. Now introduce a scientific discovery about this category, Recommanded Product: 144163-85-9.
Enantioselective C(sp(2))-H borylations of diarylmethylsilanes were catalyzed using iridium complexes with chiral pyridine-dihydroisoquinoline (PyDHIQ) ligands. High enantioselectivities (up to >99% ee) were observed for various substrates. A gram-scale synthesis was achieved using 1 mol% of the catalyst to afford a 91% yield of the desired chiral borylated organosilane product with >99% ee. (C) 2020 Elsevier Ltd. All rights reserved.
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Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare