Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: 4-(Hydroxymethyl)-1,3-dioxolan-2-one, is researched, Molecular C4H6O4, CAS is 931-40-8, about Multifunctional and Sustainable Fe-Iminopyridine Complexes for the Synthesis of Cyclic Carbonates.HPLC of Formula: 931-40-8.
The use of multifunctional and sustainable Fe catalysts for the formation of cyclic carbonates from epoxides and CO2 at 80° and 3 bar pressure is presented. The optimal catalyst possesses a halide counteranion and a H bond donor to activate the epoxide for ring opening, affording a single-component, cocatalyst-free catalytic system.
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