Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 2799-17-9, Name is (S)-1-Aminopropan-2-ol, molecular formula is C3H9NO, belongs to chiral-catalyst compound, is a common compound. In a patnet, author is Li, Gonglin, once mentioned the new application about 2799-17-9, Application In Synthesis of (S)-1-Aminopropan-2-ol.
A unique chiral amine organocatalyst with a bispidine structure was found to be efficient for the diastereo-and enantioselective Mannich reaction of isatin ketimines with ketones. A series of 3-substituted 3-amino-2-oxindoles bearing vicinal tertiary and quaternary chiral stereogenic centers were obtained in excellent yields with excellent dr and ee values. The gram-scale synthesis and transformation of the product showed the practicability of this methodology. In addition, a possible transition state model was proposed to explain the origin of the stereoselectivity.
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Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare