Reference of 1121-22-8, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 1121-22-8, Name is trans-Cyclohexane-1,2-diamine, SMILES is N[C@@H]1CCCC[C@H]1N, belongs to chiral-catalyst compound. In a article, author is Curran, Simon P., introduce new discover of the category.
A single C-2-symmetric squaramide catalyst system allows the facile addition of either malononitrile or benzyl nitroacetate to simple pyrazole-based Michael acceptors with excellent enantiocontrol and at lower catalyst loadings than previously possible. The latter reactions are not diastereoselective, however facile hydrogenolysis leads to decarboxylation and formation of the formal adduct from the addition of nitromethane (a very recalcitrant nucleophile in this chemistry) with excellent yield and enantiocontrol.
Reference of 1121-22-8, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 1121-22-8.
Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare