The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.21436-03-3, Name is (1S,2S)-Cyclohexane-1,2-diamine, molecular formula is C6H14N2. In a Article，once mentioned of 21436-03-3, Computed Properties of C6H14N2
An asymmetric aminocatalytic activation strategy to obtain enantioenriched cyclobutanes through [2 + 2] photocycloaddition under visible light irradiation is presented. This metal-free process does not require the use of any external photocatalyst, as it is catalyzed by a simple diamine which, upon condensation with an enone substrate, forms an iminium ion intermediate that absorbs in the visible light region. The direct excitation of such an intermediate leads to a charge transfer (CT) excited state that unlocks a stereocontrolled intermolecular photocycloaddition with good enantiomeric and diastereoisomeric ratios and high yields. Finally, DFT calculations and experiments were performed to support the charge transfer behavior and the mechanistic proposal.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Computed Properties of C6H14N2, you can also check out more blogs about21436-03-3