The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.14187-32-7, Name is Dibenzo-18-crown-6, molecular formula is C20H24O6. In a Article，once mentioned of 14187-32-7, Safety of Dibenzo-18-crown-6
The charge-transfer complexes of dibenzo-18-crown-6(DB18C6) (L) with iodine, as a typical sigma-acceptor, were studied spectrophotometrically in chloroform, dichloromethane and their 1:1 (v/v) mixture at 25.0 ± 0.1 C. Spectral data, formation constants and the effect of the solvent have been determined. Spectral characteristics and formation constants are discussed in the terms of donor molecular structure and solvent polarity. The stoichiometry of the complexes was established to be 1:1. The formation constants (KCT) of the complexes were determined. The complexes were isolated and characterized by FTIR and 1H-NMR spectroscopy. The observed time dependence of the charge-transfer band and subsequent formation of I3- in solution were related to the slow transformation of the initial 1:1 L:I2 outer complex to an inner electron donor-acceptor complex, followed by fast reaction of the inner complex with iodine to form a triiodide ion. The pseudo-first-order rate constants for the transformation process were evaluated in different solvent systems.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Safety of Dibenzo-18-crown-6, you can also check out more blogs about14187-32-7