Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 10466-61-2, is researched, SMILESS is N[C@@H](CC(C)C)C(N)=O.[H]Cl, Molecular C6H15ClN2OJournal, Biotechnology Techniques called Mass transfer induced interchange of the kinetic and thermodynamic control of enzymic peptide synthesis in biphasic water-organic systems, Author is Nadim, A.; Stoineva, I. B.; Galunsky, B.; Kasche, V.; Petkov, D. D., the main research direction is enzymic peptide coupling kinetics thermodn; chymotrypsin peptide coupling kinetics thermodn.Category: chiral-catalyst.
Peptide synthesis catalyzed by α-chymotrypsin in water and in biphasic water-Me iso-Bu ketone systems is compared. An interchange of the reaction control was observed in the biphasic system at high enzyme concentration due to substrate and product partitioning. Under these conditions, the rate of mass transfer between the phases was the rate-limiting step, and the hydrolysis product concentration had a transient maximum ≫ equilibrium value. In this case, most of the peptide was prepared in a thermodynamically controlled process. In the aqueous one-phase system, the peptide synthesis was kinetically controlled.
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