One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, such as the rate of change in the concentration of reactants or products with time. 10482-56-1, Name is (S)-(-)-Terpineol, formurla is C10H18O. In a document, author is Huang, Long-Tao, introducing its new discovery. Formula: C10H18O.
The enantioselective C-H alkylation of 8-ethylquinolines with enones or acrolein using a Rh-III catalyst and a chiral carboxylic acid is described. Under mild reaction conditions, a binaphthyl-based chiral carboxylic acid enables the enantioselective cleavage of the 8-ethylquinoline C(sp(3))-H bond. The obtained results demonstrate the utility of the combination of a high-valent group 9 metal catalyst and a chiral carboxylic acid for the enantioselective C(sp(3))-H activation and the subsequent C-C bond formation.
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Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare