Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 542-58-5, is researched, SMILESS is CC(OCCCl)=O, Molecular C4H7ClO2Journal, Industrial & Engineering Chemistry Research called Kinetic Study of UV Peroxidation of Bis(2-chloroethyl) Ether in Aqueous Solution, Author is Li, K. Y.; Liu, C. C.; Ni, Q.; Liu, Z. F.; Huang, F. Y. C.; Colapret, J. A., the main research direction is kinetics UV peroxidation aqueous bischloroethyl ether; mechanism UV peroxidation aqueous bischloroethyl ether.Application of 542-58-5.
Exptl. data from the UV peroxidation of bis(2-chloroethyl) ether (DCEE) in aqueous solution indicated the rate equation is 0.163[DCEE]0.61[H2O2]0.54. Important intermediates identified are 2-chloroethyl acetate, an enolic tautomer of 2-chloroethyl acetate, 2-chloroethoxyethene, 2-chloroethanol, acetaldehyde, ethylene oxide, and chloroethene. All the intermediates could be reduced to undetectable levels after 30 min of irradiation when DCEE/H2O2 initial ratio of 1/10 was used. A reaction mechanism with complex pathways through both the attack of hydroxy free radical and the direct photolysis on DCEE was proposed. Intermediate identification and the rate equation suggested that the pathways in which DCEE is attacked by hydroxy free radicals are predominant. The rate equation derived from this mechanism predicted the peroxidation of DCEE is half-order with respect to both DCEE and H2O2 concentrations
As far as I know, this compound(542-58-5)Application of 542-58-5 can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.