Simple exploration of tert-Butyl ((1R,2S,5S)-2-amino-5-(dimethylcarbamoyl)cyclohexyl)carbamate oxalate

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Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 1210348-34-7, Name is tert-Butyl ((1R,2S,5S)-2-amino-5-(dimethylcarbamoyl)cyclohexyl)carbamate oxalate, molecular formula is C16H29N3O7. In an article, author is Zhao, Hongyan,once mentioned of 1210348-34-7, Recommanded Product: 1210348-34-7.

A series of chiral organozinc complexes [(L-1)ZnEt](2) (1), [(L-2)ZnEt](2) (2) and [(L-3)ZnEt](2) (3) have been prepared by ethane elimination reaction between ZnEt2 and the corresponding chiral sulfonylamidoazetidine ligands, (1 ‘ S,2S,3S)-1-(1 ‘-Phenylethyl)-2-phenyl-3-isopropylsulfonamidoazetidine (HL1), (1 ‘ S,2S,3S)-1-(1 ‘-Phenylethyl)-2-phenyl-3-(p-tolylsulfonamido)azetidine (HL2), and (1 ‘ S,2S,3S)-1-(1 ‘-Phenylethyl)-2-phenyl-3-(m-tolylsulfona-mido)azetidine (HL3), respectively. These complexes were characterized by various spectroscopic methods and elemental analyses. The structures of 1 and 2 were further confirmed by single crystal X-ray diffraction. Complexes 1-3 are active catalysts for the ring-opening polymerization (ROP) of rac-lactide, leading to het-erotactic-rich polylactides under mild conditions.

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Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare