Some scientific research about 2,2-Biphenol

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Synthetic Route of 1806-29-7. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 1806-29-7, Name is 2,2-Biphenol. In a document type is Article, introducing its new discovery.

New chiral phosphinephosphites (R)-(5,5′-dichloro-2-diphenylphosphino-4,4′,6,6′-tetramethylbiphenyl-2′-yl)(S)-1,1′-binaphthalen-2,2′-diyl)phosphite and its enantiomer (S,R)-BIPHEMPHOS have been synthesized from 5,5′-dichloro-4,4′,6,6′-tetramethyl-2,2′-biphenyldiol in enantiomerically pure form.Their Rh(I) complexes have been shown to be highly efficient catalysts for asymmetric hydroformylations of a variety of olefinic substrates.The corresponding phosphinephosphites derived from 2,2′-biphenyldiol were also tested as ligands for asymmetric hydroformylation.

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Reference:
Chiral Catalysts,
Chiral catalysts – SlideShare