Some scientific research about 33100-27-5

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Interactions of Nitrosonium Salts with Crown Ethers

Interactions of nitrosonium tetrafluoroborate and hexafluorophosphate with 18-crown-6, 15-crown-5, and 12-crown-4 in dichloromethane, acetonitrile, and nitromethane have been probed by a combination of proton magnetic resonance spectroscopy, infrared spectroscopy, and conductance measurements.The stoichiometries of the crown ether-nitrosonium salt complexes were one mole of 18-crown-6 per mole of nitrosonium salt and two moles of nitrosonium salt in all solvents.For 15-crown-5, the one-to-one stoichiometry observed in acetonitrile and nitromethane changed to two moles of crown ether per mole of nitrosonium salt in dichloromethane.The nature of these complexes is discussed.Treatment of a solution of equimolar nitrosonium hexafluorophosphate and 18-crown-6 in dichloromethane with water produced hydronium hexafluorophosphate.18-crown-6 complex.

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Chiral Catalysts,
Chiral catalysts – SlideShare