In an article, author is Liu, Wei, once mentioned the application of 80657-57-4, Name is (S)-Methyl 3-hydroxy-2-methylpropanoate, molecular formula is C5H10O3, molecular weight is 118.1311, MDL number is MFCD00064520, category is chiral-catalyst. Now introduce a scientific discovery about this category, Category: chiral-catalyst.
A versatile kinetic resolution of protecting-group-free BINAMs and NOBINs has been realized through chiral phosphoric acid catalyzed triazane formation with azodicarboxylates. A series of mono-N-protected and unprotected BINAMs, diphenyl diamines and NOBIN derivatives could be kinetically resolved with excellent performances (with s factor up to 420). The gram-scale reactions and facile derivatizations of the chiral products demonstrate the potential of these methods in the asymmetric synthesis of chiral catalysts and ligands.
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Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare