Sources of common compounds: 13925-00-3

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Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 13925-00-3, is researched, Molecular C6H8N2, about Crystal structure of a low-spin poly[di-μ3-cyanido-di-μ2-cyanido-bis(μ2-2-ethylpyrazine)dicopper(I)iron(II)], the main research direction is iron copper complex crystal structure crystallization; bimetallic; copper(I); crystal structure; di­cyano­cuprate; ethyl­pyrazine; iron(II); metal–organic framework.Recommanded Product: 13925-00-3.

In the title metal-organic framework, [Fe(C6H8N2)2{Cu(CN)2}2]n, the low-spin FeII ion lies at an inversion center and displays an elongated octahedral [FeN6] coordination environment. The axial positions are occupied by two symmetry-related bridging 2-ethylpyrazine ligands, while the equatorial positions are occupied by four N atoms of two pairs of symmetry-related cyanide groups. The CuI center is coordinated by three cyanide carbon atoms and one N atom of a bridging 2-ethylpyrazine mol., which form a tetrahedral coordination environment. Two neighboring Cu atoms have a short Cu···Cu contact [2.4662 (7) Å] and their coordination tetrahedra are connected through a common edge between two C atoms of cyanide groups. Each Cu2(CN)2 unit, formed by two neighboring Cu atoms bridged by two carbons from a pair of μ-CN groups, is connected to six FeII centers via two bridging 2-ethylpyrazine mols. and four cyanide groups, resulting in the formation of a polymeric three-dimensional metal-organic coordination framework.

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Reference:
Chiral Catalysts,
Chiral catalysts – SlideShare