Electric Literature of 33100-27-5. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 33100-27-5, Name is 1,4,7,10,13-Pentaoxacyclopentadecane. In a document type is Article, introducing its new discovery.
Stereochemical Role of Lone Pairs in Main-group Elements. Part 3. Structure and Bonding in Trichloro(1,4,7,10,13-pentaoxacyclopentadecane)antimony(III) studied by Means of X-ray Crystallography at 120 K
The crystal structure of the complex formed between SbCl3 and 15-crown-5 (1,4,7,10,13,-pentaoxacyclopentadecane,L) has been determined from X-ray diffractometer data by Patterson and Fourier methods.Crystals are orthorhombic, space group P212121, with Z = 4 in a unit cell of dimensions a = 7.575(1), b = 12.734(2), and c = 15.838(3) Angstroem.The structure, refined to R = 0.033 for 1989 observed reflections, consists of discrete SbCl3L molecules in which antimony is sandwiched between essentially parallel planes containing five oxygens and three chlorines, respectively.
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Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare