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Benzo- and dibenzo-crown ethers substituted with (azulene-1-yl) azo chromophores. Synthesis and properties

Colored benzo- and dibenzo-crown ethers with (azulene-1-yl) azo chromophores(s) at benzo ring(s) were synthesized in good yields starting from the amines of the benzo- and dibenzo-crown ethers which were diazotized and coupled with azulenes. The obtained crown ethers were characterized and several properties of the generated new dyes were investigated (electronic and NMR-spectra, as well as pKa values, the lipophilicity and the coordination with metal cations).

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Reference£º
Chiral Catalysts,
Chiral catalysts – SlideShare