Chemistry is an experimental science, Quality Control of (S)-(-)-Terpineol, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 10482-56-1, Name is (S)-(-)-Terpineol, molecular formula is C10H18O, belongs to chiral-catalyst compound. In a document, author is Jerome, Peter.
Chiral and achiral Pd(II)-NNN pincer complexes (1-3) containing acetonitrile as an ancillary ligand were synthesized and characterized by spectroscopic (UV-visible, FT-IR, NMR and mass) techniques. Polarimetric experiments were employed to measure the specific rotation values of the chiral complexes {[alpha](D)(27)= +135 degrees (2) and -136 degrees (3)}. The structures resolved through single crystal X-ray diffraction technique disclosed the distorted square planar geometry of the complexes. Transfer hydrogenation (TH) reactions of ketones were carried out in order to appraise the catalytic efficiency of the complexes. Remarkably, the TH results were promising for all the complexes, however, the chiral complexes (2 and 3) failed to induce chirality. Further probe led us to believe that the pincer complexes turned into Pd particles in situ and the later acted as an active catalyst. The scope of TH was extended to various substituted aromatic and heterocyclic ketones (Conversions=75-99%).
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 10482-56-1. Quality Control of (S)-(-)-Terpineol.
Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare