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Reaction of a solution of copper(II) acetate in methanol with ethyl (aminomethylene)cyanoacetate derivatives 10 (H2L4) or 13 (H2L5) yields the corresponding 1D-coordination polymers 11 (infinite) and 14 (infinite), respectively.The products are insoluble in non-coordinating solvents and thermally highly stable.The structures of 11 and 14 have been established by X-ray diffraction.The one-dimensional coordination polymers 11 and 14 have different geometries, depending on the lateral group of the ligands. – Key Words: (Aminomethylene)cyanoacetate, ethyl, derivatives / Coordination polymers, 1D / Self-organization, spontaneous / Copper complexes
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Reference：
Chiral Catalysts,
Chiral catalysts – SlideShare