Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 10482-56-1, Name is (S)-(-)-Terpineol, SMILES is CC(O)([C@@H]1CC=C(C)CC1)C, in an article , author is Iribarren, Inigo, once mentioned of 10482-56-1, Quality Control of (S)-(-)-Terpineol.
A wide variety of asymmetric transformations catalysed by chiral catalysts have been developed for the synthesis of valuable organic compounds in the past several decades. Within the asymmetric catalysis field, phase-transfer catalysis has been recognized as a powerful method for establishing useful procedures for organic synthesis. In the present study intermolecular interactions between a well-known alkaloid quinine-derived phase transfer catalyst and four different anions were characterised, analysing the competition between the pure ion-pair interaction and the intermolecular hydrogen bond established upon complexation. Finally, a theoretical study of the free-energy profile corresponding to the enantioselective conjugate cyanation of an alpha,beta-unsaturated ketone in the presence of two different catalysts was performed.
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Reference:
Chiral Catalysts,
,Chiral catalysts – SlideShare